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Of these, HNE and MDA, acrolein, and crotonaldehyde have been shown to modify DNA bases, yielding promutagenic lesions and to contribute to the mutagenic and carcinogenic effects associated with oxidative stress-induced lipid peroxidation and HNE and MDA implicated carcinogenesis
Moreover, since eukaryotes segregate the TCA cycle within the mitochondria while RNR is exclusively cytosolic [86], it is unlikely that the eukaryotic TCA cycle could be similarly modified to directly support DNA precursor production
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